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Synthesis and Isolation of a Stable, Axially-Chiral Seven-Membered N-Heterocyclic Carbene
A chiral seven-membered N-heterocyclic carbene (NHC) has been synthesized from its phenol adduct (NHC-HOPh) by a novel base-induced α-elimination method, and its donor strength has been determined from the IR stretching frequencies of the NHC-Rh(CO)(2)Cl complex.
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2790814/ https://ncbi.nlm.nih.gov/pubmed/19290359 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b902460c |
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