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Substituent Effects on the Thermodynamic Stability of Imines Formed from Glycine and Aromatic Aldehydes: Implications for the Catalytic Activity of Pyridoxal-5'-Phosphate (PLP)
Equilibrium constants for addition of glycine to substituted benzaldehydes to form the corresponding imines and pK(a)s for ionization of the iminium ions were determined by (1)H NMR analysis in D(2)O. The introduction of a phenoxide anion substituent into the aromatic ring of benzaldehyde leads to a...
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| Autors principals: | , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2009
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2788968/ https://ncbi.nlm.nih.gov/pubmed/19807092 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja906230n |
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