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Fluoro-Julia Olefination as a Mild, High-Yielding Route to α-Fluoro Acrylonitriles
[Image: see text] Synthesis of a novel, stable reagent (1,3-benzothiazol-2-ylsulfonyl)fluoroacetonitrile from readily available ethyl α-(1,3-benzothiazol-2-ylsulfanyl)- α-fluoroacetate is reported. Aldehydes undergo condensations with (1,3-benzothiazol-2-ylsulfonyl)fluoroacetonitrile in the presence...
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| Main Authors: | , , |
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| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2008
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2771215/ https://ncbi.nlm.nih.gov/pubmed/18841918 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo801235x |
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