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Enantiomerization Dynamics and a Catalytic Dynamic Resolution of N-Trimethylallyl-2-lithiopyrrolidine

[Image: see text] The barriers to enantiomerization of N-trimethylallyl-2-lithiopyrrolidine have been measured in the presence of sparteine, 1, N,N′-diisopropylbispidine, 2, and diaminoalkoxide 3. We have additionally demonstrated a rare example of a catalytic dynamic resolution using either of two...

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Détails bibliographiques
Auteurs principaux: Beng, Timothy K., Yousaf, Taher I., Coldham, Iain, Gawley, Robert E.
Format: Artigo
Langue:Inglês
Publié: 2009
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC2768471/
https://ncbi.nlm.nih.gov/pubmed/19405472
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja900755a
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