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Palladium-Catalyzed Carbonylation Reactions of Aryl Bromides at Atmospheric Pressure: A General System Based on Xantphos

A method for the Pd-catalyzed carbonylation of aryl bromides has been developed using Xantphos as the ligand. This method is effective for the direct synthesis of Weinreb amides, 1° and 2° benzamides and methyl esters from the corresponding aryl bromides at atmospheric pressure. In addition, a putat...

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Detalhes bibliográficos
Main Authors: Martinelli, Joseph R., Watson, Donald A., Freckmann, Dominique M. M., Barder, Timothy E., Buchwald, Stephen L.
Formato: Artigo
Idioma:Inglês
Publicado em: 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2756424/
https://ncbi.nlm.nih.gov/pubmed/18720970
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo801279r
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