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Palladium-Catalyzed Amination of Aryl Chlorides and Bromides with Ammonium Salts

[Image: see text] We report the palladium-catalyzed coupling of aryl halides with ammonia and gaseous amines as their ammonium salts. The coupling of aryl chlorides and ortho-substituted aryl bromides with ammonium sulfate forms anilines with higher selectivity for the primary arylamine over the dia...

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Publicado en:Org Lett
Autores principales: Green, Rebecca A., Hartwig, John F.
Formato: Artigo
Lenguaje:Inglês
Publicado: American Chemical Society 2014
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC4260968/
https://ncbi.nlm.nih.gov/pubmed/25133675
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol501739g
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