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Kinetics and Activation Parameters for Oxidations of Styrene by Compounds I from Cytochrome P450(BM-3) (CYP102A1) Heme Domain and from CYP119

Cytochrome P450 (CYP or P450) enzymes are ubiquitous in nature where they catalyze a vast array of oxidation reactions. The active oxidants in P450s have long been assumed to be iron(IV)-oxo porphyrin radical cations termed Compounds I, but P450 Compounds I have proven difficult to prepare. The rece...

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Detalhes bibliográficos
Main Authors: Yuan, Xinting, Wang, Qin, Horner, John H., Sheng, Xin, Newcomb, Martin
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2755501/
https://ncbi.nlm.nih.gov/pubmed/19708688
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi901258m
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