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NMR spectroscopy and molecular modelling studies of nitrosylcobalamin: further evidence that the deprotonated, base-off form is important for nitrosylcobalamin in solution
The structure of nitrosylcobalamin (NOCbl) in solution has been studied by NMR spectroscopy and the (1)H and (13)C NMR spectra have been assigned. (13)C and (31)P NMR chemical shifts, the UV-vis spectrum of NOCbl and the observed pK (base-off) value of ~5.1 for NOCbl provide evidence that a signific...
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Main Authors: | , , , , , |
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Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
2008
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2754767/ https://ncbi.nlm.nih.gov/pubmed/19122899 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b810895a |
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