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NMR spectroscopy and molecular modelling studies of nitrosylcobalamin: further evidence that the deprotonated, base-off form is important for nitrosylcobalamin in solution

The structure of nitrosylcobalamin (NOCbl) in solution has been studied by NMR spectroscopy and the (1)H and (13)C NMR spectra have been assigned. (13)C and (31)P NMR chemical shifts, the UV-vis spectrum of NOCbl and the observed pK (base-off) value of ~5.1 for NOCbl provide evidence that a signific...

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Detalhes bibliográficos
Main Authors: Hassanin, Hanaa A., Hannibal, Luciana, Jacobsen, Donald W., Brown, Kenneth L., Marques, Helder M., Brasch, Nicola E.
Formato: Artigo
Idioma:Inglês
Publicado em: 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2754767/
https://ncbi.nlm.nih.gov/pubmed/19122899
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b810895a
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