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Cleavage of [4Fe-4S]-Type Clusters: Breaking the Symmetry
The cleavage of [4Fe-4S]-type clusters is thought to be important in proteins such as Fe-S scaffold proteins and nitrogenase. However, most [4Fe-4S](2+) clusters in proteins have two antiferromagnetically coupled high-spin layers in which a minority spin is delocalized in each layer, thus forming a...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2754062/ https://ncbi.nlm.nih.gov/pubmed/19378967 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp900402y |
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