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Probing Ligand Effects on the Redox Energies of [4Fe-4S] Clusters Using Broken-Symmetry Density Functional Theory
A central issue in understanding redox properties of iron-sulfur proteins is determining the factors that tune the reduction potentials of the Fe-S clusters. Recently, Solomon and co-workers have shown that the Fe—S bond covalency of protein analogs measured by %L, the percent ligand character of th...
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| 主要な著者: | , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2009
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2692907/ https://ncbi.nlm.nih.gov/pubmed/19378988 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp809446q |
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