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Preparation of 2,3-Disubstituted Indoles by Sequential Larock Heteroannulation and Silicon-Based Cross-Coupling Reactions

A simple and convergent synthesis of 2,3-disubstituted indoles has been developed using a sequential Larock indole synthesis and silicon-based, cross-coupling reaction. Substituted 2-iodoanilines reacted with an alkynyldimethylsilyl tert-butyl ether to afford indole-2-silanols under the Larock heter...

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Detalhes bibliográficos
Main Authors: Denmark, Scott E., Baird, John D.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2752212/
https://ncbi.nlm.nih.gov/pubmed/19784400
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2008.10.043
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