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A Catalytic, Brønsted Base Strategy for Intermolecular Allylic C—H Amination
A Brønsted base activation mode for oxidative, Pd(II)/sulfoxide catalyzed, intermolecular C—H allylic amination is reported. N,N-diisopropylethylamine was found to promote amination of unactivated terminal olefins, forming the corresponding linear allylic amine products with high levels of stereo-,...
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| Hauptverfasser: | , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2009
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2751613/ https://ncbi.nlm.nih.gov/pubmed/19645492 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja903939k |
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