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A Catalytic, Brønsted Base Strategy for Intermolecular Allylic C—H Amination

A Brønsted base activation mode for oxidative, Pd(II)/sulfoxide catalyzed, intermolecular C—H allylic amination is reported. N,N-diisopropylethylamine was found to promote amination of unactivated terminal olefins, forming the corresponding linear allylic amine products with high levels of stereo-,...

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Detalhes bibliográficos
Main Authors: Reed, Sean A., Mazzotti, Anthony R., White, M. Christina
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2751613/
https://ncbi.nlm.nih.gov/pubmed/19645492
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja903939k
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