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Pyridoxal 5'-Phosphate: Electrophilic Catalyst Extraordinaire
Studies of nonenzymatic electrophilic catalysis of carbon deprotonation of glycine show that pyridoxal 5'-phosphate (PLP) strongly enhances the carbon acidity of α-amino acids, but that this is not the overriding mechanistic imperative for cofactor catalysis. Although the fully protonated PLP-g...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2009
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2749917/ https://ncbi.nlm.nih.gov/pubmed/19640775 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.cbpa.2009.06.023 |
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