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Dependence of the AmII′p Proline Raman Band on Peptide Conformation
We utilized UV-resonance Raman (UVRR) measurements and density functional theory (DFT) calculations to relate that the AmII′p frequency to the ψ-angle. The AmII′p frequency shifts by ∼ 25 cm(-1) as the ψ-angle is varied over allowed angles of the pro peptide bond. The AmII′p frequency does not show...
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| Autors principals: | , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2009
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2742972/ https://ncbi.nlm.nih.gov/pubmed/19627094 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp809857y |
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