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On the Mechanism of Pd(0)-Catalyzed, Cu(I) Carboxylate-Mediated Thioorganic-Boronic Acid Desulfitative Coupling. A Non-innocent Role for Carboxylate Ligand

Computational studies of the mechanism of the Pd-catalyzed, Cu(I)-carboxylate-mediated desulfitative coupling of thioorganics with boronic acids have determined that the requisite Cu(I)-carboxylate plays multiple important roles. The Cu(I)-carboxylate enhances both the transmetalation and the C-C re...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Musaev, Djamaladdin G., Liebeskind, Lanny S.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2009
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2742425/
https://ncbi.nlm.nih.gov/pubmed/20161122
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om900602b
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