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Cobalt-Mediated [3+2]-Annulation Reaction of Alkenes with α,β-Unsaturated Ketones and Imines

[Image: see text] The utility of cobalt dinitrosyl complexes for the [3+2] annulation of alkenes with unsaturated enones and ketimines has been demonstrated. Reaction of a series of cobalt dinitrosyl/alkene adducts with conjugate acceptors in the presence of Sc(OTf)(3)/LHMDS formed two new C-C bonds...

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Autors principals: Schomaker, Jennifer M., Toste, F. Dean, Bergman, Robert G.
Format: Artigo
Idioma:Inglês
Publicat: 2009
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2736344/
https://ncbi.nlm.nih.gov/pubmed/19639989
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol901542n
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