Characterization of the Fe Site in Iron-Sulfur-Cluster-Free Hydrogenase (Hmd) and of a Model Compound via Nuclear Resonance Vibrational Spectroscopy (NRVS)

We have used (57)Fe nuclear resonance vibrational spectroscopy (NRVS) to study the iron site in the iron-sulfur-cluster-free hydrogenase Hmd from the methanogenic archaeon Methanothermobacter marburgensis. The spectra have been interpreted by comparison with a cis-(CO)(2)-ligated Fe model compound,...

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Hauptverfasser: Guo, Yisong, Wang, Hongxin, Xiao, Yuming, vogt, Sonja, Thauer, Rudolf K., Shima, Seigo, Volkers, Phillip I., Rauchfuss, Thomas B., Pelmentschikov, Vladimir, Case, David A., Alp, Ercan E., Sturhahn, Wolfgang, Yada, Yoshitaka, Cramer, Stephen P.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2008
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2734977/
https://ncbi.nlm.nih.gov/pubmed/18407624
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic701251j
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