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The Millisecond Intermediate in the Reaction of Nitric Oxide with Oxymyoglobin is an iron(III)-Nitrato Complex, not a Peroxynitrite

[Image: see text] The dioxygenation of nitric oxide by oxyheme in globin proteins is a major route for NO detoxification in aerobic biological systems. In myoglobin, this reaction is thought to proceed through an iron(III)-bound peroxynitrite before homolytic cleavage of the O-O bond to form an iron...

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Detalhes bibliográficos
Main Authors: Yukl, Erik T., de Vries, Simon, Moënne-Loccoz, Pierre
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2734454/
https://ncbi.nlm.nih.gov/pubmed/19469573
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja9026924
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