Allylic Oxidations Catalyzed by Dirhodium Caprolactamate via Aqueous tert-Butyl Hydroperoxide: The Role of the tert-Butylperoxy Radical

[Image: see text] Dirhodium(II) caprolactamate exhibits optimal efficiency for the production of the tert-butylperoxy radical, which is a selective reagent for hydrogen atom abstraction. These oxidation reactions occur with aqueous tert-butyl hydroperoxide (TBHP) without rapid hydrolysis of the capr...

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Autores principales: McLaughlin, Emily C., Choi, Hojae, Wang, Kan, Chiou, Grace, Doyle, Michael P.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2009
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Article
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC2730049/
https://ncbi.nlm.nih.gov/pubmed/19072696
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo8021132
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