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Strategic use of nickel(0)-catalyzed enyne-epoxide reductive coupling towards the synthesis of (−)-cyatha-3,12-diene
Various situations are explored in which the nickel(0)-catalyzed enyne-epoxide reductive coupling was utilized to access key intermediates towards the total synthesis of (−)-cyatha-3,12-diene (1). Enantioenriched 3,5-dien-1-ols with a variety of functionality were obtained in a straightforward manne...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2716032/ https://ncbi.nlm.nih.gov/pubmed/20161213 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2008.11.086 |
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