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Metal-independent decomposition of hydroperoxides by halogenated quinones: Detection and identification of a quinone ketoxy radical

We have shown recently that halogenated quinones could enhance the decomposition of hydroperoxides and formation of alkoxyl/hydroxyl radicals through a metal-independent mechanism. However, neither the proposed quinone enoxy radical intermediate, nor the major reaction products were unambiguously id...

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Main Authors: Zhu, Ben-Zhan, Shan, Guo-Qiang, Huang, Chun-Hua, Kalyanaraman, Balaraman, Mao, Li, Du, Yu-Guo
Formato: Artigo
Idioma:Inglês
Publicado: National Academy of Sciences 2009
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC2710671/
https://ncbi.nlm.nih.gov/pubmed/19556549
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0900065106
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