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O(2) reduction by a functional heme/nonheme bis-iron NOR model complex

O(2) reactivity of a functional NOR model is investigated by using electrochemistry and spectroscopy. The electrochemical measurements using interdigitated electrodes show very high selectivity for 4e O(2) reduction with minimal production of partially reduced oxygen species (PROS) under both fast a...

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Bibliographic Details
Main Authors: Collman, James P., Dey, Abhishek, Yang, Ying, Ghosh, Somdatta, Decréau, Richard A.
Format: Artigo
Language:Inglês
Published: National Academy of Sciences 2009
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2705577/
https://ncbi.nlm.nih.gov/pubmed/19541624
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0904634106
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