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A Cu(I)-Catalyzed C-H α-Amination of Aryl Ketones. Direct Synthesis of Imidazolinones

[Image: see text] This paper describes an α-amination process of aryl ketones using CuCl as catalyst and di-tert-butyldiaziridinone as the nitrogen source. A variety of imidazolinone derivatives are prepared in moderate yields under mild conditions. A possible catalytic cycle is proposed for this re...

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Detalhes bibliográficos
Main Authors: Zhao, Baoguo, Du, Haifeng, Shi, Yian
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2704946/
https://ncbi.nlm.nih.gov/pubmed/19402696
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo9004553
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