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Studies on Paraherquamide Biosynthesis: Synthesis of Deuterium-Labeled 7-Hydroxy-Pre-Paraherquamide, a Putative Precursor of Paraherquamides A, E & F
The stereocontrolled, asymmetric synthesis of triply deuterium-labeled 7-hydroxy-pre-paraherquamide (27) was accomplished, employing a diastereoselective intramolecular S(N)2′ cyclization strategy. The deuterium-labeled substrate was interrogated in a precursor incorporation experiment in the parahe...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2699280/ https://ncbi.nlm.nih.gov/pubmed/20161298 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2008.08.102 |
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