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A short stereoselective synthesis of (+)-(6R,2′S)-cryptocaryalactone via ring-closing metathesis

A short stereoselective synthesis of (+)-(6R,2′S)-cryptocaryalactone was successfully completed. Key steps included the application of Carreira’s asymmetric alkynylation reaction to form a propargylic alcohol and subsequently lactone formation using the powerful ring-closing metathesis reaction.

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Autori principali: Radha Krishna, Palakodety, Lopinti, Krishnarao, Reddy, K L N
Natura: Artigo
Lingua:Inglês
Pubblicazione: Beilstein-Institut 2009
Soggetti:
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC2686312/
https://ncbi.nlm.nih.gov/pubmed/19478909
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.5.14
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