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Direct Asymmetric Michael Addition to Nitroalkenes: Vinylogous Nucleophilicity Under Dinuclear Zinc Catalysis
[Image: see text] Under dinuclear catalysis, the direct conjugate addition of 2(5H)-furanone to nitroalkenes involves the γ-position of the nucleophile. The synthetically versatile Michael adducts are prepared in good yields, with high levels of diastereo- and enantioselectivity. A model is presente...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2679032/ https://ncbi.nlm.nih.gov/pubmed/19281239 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja809723u |
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