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De Novo Approach to 2-Deoxy-β-Glycosides: Asymmetric Syntheses of Digoxose and Digitoxin1
[Image: see text] A highly enantioselective and straightforward route to trisaccharide natural product digoxose and digitoxin has been developed. Key to this approach is the iterative application of the palladium-catalyzed glycosylation reaction, reductive 1,3-transposition, diastereoselective dihyd...
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| Autors principals: | , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2007
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2678957/ https://ncbi.nlm.nih.gov/pubmed/17338573 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo062534+ |
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