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Ruthenium-Catalyzed Cycloisomerization-6π-Cyclization: A Novel Route to Pyridines

[Image: see text] Herein we report a method for the synthesis of substituted pyridines. The unsaturated ketones and aldehydes derived from the cycloisomerization of primary and secondary propargyl diynols in the presence of [CpRu(CH(3)CN)(3)]PF(6) (1) are converted to 1-azatrienes which in turn unde...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Trost, Barry M., Gutierrez, Alicia C.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2007
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC2678947/
https://ncbi.nlm.nih.gov/pubmed/17362020
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol070163t
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