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Tandem Ruthenium-Catalyzed Redox Isomerization–O-Conjugate Addition: An Atom-Economic Synthesis of Cyclic Ethers

[Image: see text] An atom-economical method for the convenient synthesis of tetrahydropyrans and tetrahydrofurans is reported. Enones and enals derived from the [IndRu(PPh(3))(2)Cl]-catalyzed redox-isomerization of primary and secondary propargyl alcohols undergo a subsequent intramolecular conjugat...

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Autors principals: Trost, Barry M., Gutierrez, Alicia C., Livingston, Robert C.
Format: Artigo
Idioma:Inglês
Publicat: 2009
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2728751/
https://ncbi.nlm.nih.gov/pubmed/19449896
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol9007876
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