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Does Neighboring Group Participation by Non-Vicinal Esters Play a Role in Glycosylation Reactions? Effective Probes for the Detection of Bridging Intermediates
[Image: see text] Neighboring group participation in glycopyranosylation reactions is probed for esters at the 3-O-axial and equatorial, 4-O-axial and equatorial, and 6-O-sites of a range of donors through the use tert-butoxycarbonyl esters. The anticipated intermediate cyclic dioxanyl cation is int...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2669227/ https://ncbi.nlm.nih.gov/pubmed/18939876 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo801630m |
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