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Preparation of Substituted Enol Derivatives From Terminal Alkynes and Their Synthetic Utility
[Image: see text] Stereodefined enol derivatives of aldehydes are prepared from terminal alkynes. Specifically, terminal alkynes are known to undergo Cp(2)ZrCl(2)-catalyzed methylalumination. Here, we show that the resultant vinylalanes can be oxygenated with peroxyzinc species to generate trisubsti...
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| Hauptverfasser: | , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2008
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2668979/ https://ncbi.nlm.nih.gov/pubmed/18517202 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja803480b |
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