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Cyclopentadienone Iron Alcohol Complexes: Synthesis, Reactivity, and Implications for the Mechanism of Iron Catalyzed Hydrogenation of Aldehydes
Cyclopentadienone iron alcohol complexes generated from the reactions of [2,5-(SiMe(3))(2)-3,4-(CH(2))(4)(η(5)-C(4)COH)]Fe(CO)(2)H (3) and aldehydes were characterized by (1)H NMR, (13)C NMR, and IR spectroscopy. The benzyl alcohol complex [2,5-(SiMe(3))(2)-3,4-(CH(2))(4)(η(5)-C(4)C=O)]Fe(CO)(2)(HOC...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2664094/ https://ncbi.nlm.nih.gov/pubmed/19193034 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja808683z |
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