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Interrupting the Nazarov Cyclization with Indoles
[Image: see text] A carbon-terminated interrupted Nazarov reaction is described. The trimethylsilyl enol ethers derived from propargyl vinyl ketones undergo selective proton transfer at the distal acetylenic carbon atom to provide allenyl vinyl ketones as transient intermediates. In the presence of...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2008
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2663042/ https://ncbi.nlm.nih.gov/pubmed/18720989 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol801587u |
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