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Origins of Stereoselectivity in the Oxido-Alkylidenation of Alkynes
[Image: see text] A mild, convenient oxido-alkylidenation of alkynes is described. The three-step sequence involves the 1,3-dipolar cycloaddition of a nitrone and an alkynoate, oxidation of the resulting isoxazoline, and stereoselective extrusion of nitrosomethane. Quantum mechanical calculations id...
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2662994/ https://ncbi.nlm.nih.gov/pubmed/18798638 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol8019154 |
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