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Efficient Dehydrogenation of Amines and Carbonyl Compounds Catalyzed by a Tetranuclear Ruthenium-μ-Oxo-μ-Hydroxo-Hydride Complex
The tetranuclear ruthenium-μ-oxo–μ-hydroxo-hydride complex {[(PCy(3))(CO)RuH](4)(μ(4)-O)(μ(3)-OH)(μ(2)-OH)} (1) was found to be a highly effective catalyst for the transfer dehydrogenation of amines and carbonyl compounds. For example, the initial turnover rate of the dehydrogenation of 2-methylindo...
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| Main Authors: | , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2009
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2658527/ https://ncbi.nlm.nih.gov/pubmed/20119477 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om8010883 |
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