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Preparation of Bicyclic 1,2,4-Trioxanes from γ,δ-Unsaturated Ketones
[Image: see text] Treatment of γ,δ-unsaturated ketones with hydrogen peroxide and acid provides a rapid entry into the medicinally important 1,2,4-trioxane structure. Alkene substitution that stabilizes carbocationic intermediates proved to be important for the success of this transformation.
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| Glavni autori: | , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2009
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2657341/ https://ncbi.nlm.nih.gov/pubmed/19132925 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol8022853 |
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