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Nucleophilic Addition of Organozinc Reagents to 2-Sulfonyl Cyclic Ethers: Stereoselective Synthesis of Manassantins A and B

[Image: see text] A convergent route to the synthesis of manassantins A and B, potent inhibitors of HIF-1, is described. Central to the synthesis is a stereoselective addition of an organozinc reagent to a 2-benzenesulfonyl cyclic ether to achieve the 2,3-cis-3,4-trans-4,5-cis-tetrahydrofuran of the...

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Main Authors: Kim, Hyoungsu, Kasper, Amanda C., Moon, Eui Jung, Park, Yongho, Wooten, Ceshea M., Dewhirst, Mark W., Hong, Jiyong
Format: Artigo
Jezik:Inglês
Izdano: 2009
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC2656112/
https://ncbi.nlm.nih.gov/pubmed/19111058
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol8024617
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