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Stereoselective, Dual-Mode Ruthenium-Catalyzed Ring-Expansion of Alkynylcyclopropanols
A novel, dual-pathway ring-expansion of alkynylcyclopropanols is described. On treatment with a ruthenium catalyst, these compounds undergo highly selective enlargement to either (Z)-alkylidene cyclobutanones or β-substituted cyclopentenones. The unique ability to access the least selective double b...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2655345/ https://ncbi.nlm.nih.gov/pubmed/19053484 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja807894t |
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