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Novel dimethoxy(aminoalkoxy)borate derived from (S)-diphenylprolinol as highly efficient catalyst for the enantioselective boron-mediated reduction of prochiral ketones
The novel dimethoxyl(aminoalkoxy)borate 1 was isolated as a white crystalline dimer joined by H–bonding as evidenced by X-ray analysis, and demonstrated to be a highly effective catalyst for the asymmetric reduction of representative prochiral ketones with borane-DMS. Optically pure alcohols were ob...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2654321/ https://ncbi.nlm.nih.gov/pubmed/20160845 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2008.12.061 |
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