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Inversion of Configuration at the Metal in Diastereomeric Imido Alkylidene Monoaryloxide Monopyrrolide (MAP) Complexes of Molybdenum
[Image: see text] The two diastereomers of Mo(NAr)(CHCMe(2)Ph)(2,5-dimethylpyrrolide)(1) ((S(M)R(1))-2 and (R(M)R(1))-2, respectively, where 1 is an enantiomerically pure (R) phenoxide and Ar = 2,6-diisopropylphenyl), form adducts with PMe(3). One of these ((R(M)R(1))-2(PMe(3))) has been isolated. A...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2652865/ https://ncbi.nlm.nih.gov/pubmed/19086901 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja808308e |
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