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Magnesium-Catalyzed Asymmetric Direct Aldol Addition of Ethyl Diazoacetate to Aromatic, Aliphatic, and α,β-Unsaturated Aldehydes
[Image: see text] Magnesium-catalyzed enantioselective aldol between ethyl diazoacetate and aromatic, aliphatic, and α,β-unsaturated aldehydes affords α-diazo-β-hydroxy-esters in high enantioselectivities. Aldol adducts resulting from this asymmetric transformation are versatile intermediates toward...
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| Hlavní autoři: | , , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2009
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2652472/ https://ncbi.nlm.nih.gov/pubmed/19191696 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja809181m |
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