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Urea, but not guanidinium, destabilizes proteins by forming hydrogen bonds to the peptide group

The mechanism by which urea and guanidinium destabilize protein structure is controversial. We tested the possibility that these denaturants form hydrogen bonds with peptide groups by measuring their ability to block acid- and base-catalyzed peptide hydrogen exchange. The peptide hydrogen bonding fo...

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Detalhes bibliográficos
Main Authors: Lim, Woon Ki, Rösgen, Jörg, Englander, S. Walter
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2650309/
https://ncbi.nlm.nih.gov/pubmed/19196963
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0812588106
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