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The cis-Δ(2,3)-double bond of phoslactomycins is generated by a post-PKS tailoring enzyme
The antifungal phoslactomycins (PLM A-F), produced by Streptomyes sp HK803, are structurally unusual in that three of their four double bonds are in the cis form (Δ(12,13), Δ(14,15), Δ(2,3)). The PLM polyketide synthase (PKS) has the predicted dehydratase catalytic domain in modules 1,2 and 5 requir...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2644895/ https://ncbi.nlm.nih.gov/pubmed/18714992 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja8044162 |
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