Llwytho...

Diels–Alder Exo-Selectivity in Terminal-Substituted Dienes and Dienophiles: Experimental Discoveries and Computational Explanations

The Diels–Alder reactions of a series of silyloxydienes and silylated dienes with acyclic α,β-unsaturated ketones and N-acyloxazolidinones have been investigated. The endo/exo stereochemical outcome is strongly influenced by the substitution pattern of the reactants. High exo selectivity was observe...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Lam, Yu-hong, Cheong, Paul Ha-Yeon, Mata, José M. Blasco, Stanway, Steven J., Gouverneur, Véronique, Houk, K. N.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2009
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC2635921/
https://ncbi.nlm.nih.gov/pubmed/19154113
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja8079548
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