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Large Ground-State Entropy Changes for Hydrogen Atom Transfer Reactions of Iron Complexes
Reported herein are the hydrogen atom transfer (HAT) reactions of two closely related dicationic iron tris α-diimine complexes. Fe(II)(H(2)bip) (iron(II) tris[2,2′-bi-1,4,5,6-tetra-hydropyrimidine]diperchlorate) and Fe(II)(H(2)bim) (iron(II) tris[2,2′-bi-2-imidazoline]diperchlorate) both transfer H(...
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| Hoofdauteurs: | , , |
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| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
2007
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2628630/ https://ncbi.nlm.nih.gov/pubmed/17402735 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja0686918 |
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