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Large Ground-State Entropy Changes for Hydrogen Atom Transfer Reactions of Iron Complexes

Reported herein are the hydrogen atom transfer (HAT) reactions of two closely related dicationic iron tris α-diimine complexes. Fe(II)(H(2)bip) (iron(II) tris[2,2′-bi-1,4,5,6-tetra-hydropyrimidine]diperchlorate) and Fe(II)(H(2)bim) (iron(II) tris[2,2′-bi-2-imidazoline]diperchlorate) both transfer H(...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Mader, Elizabeth A., Davidson, Ernest R., Mayer, James M.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2007
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC2628630/
https://ncbi.nlm.nih.gov/pubmed/17402735
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja0686918
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