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Efficient Glycosidation of a Phenyl Thiosialoside Donor with Diphenyl Sulfoxide and Triflic Anhydride in Dichloromethane
[Image: see text] The formation of sialic glycosides using a thiosialic acid derivative, diphenyl sulfoxide and trifluoromethanesulfonic anhydride is reported. With an excess of diphenyl sulfoxide glycal formation can be completely suppressed and excellent yields are obtained for coupling to a wide...
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| Autors principals: | , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2006
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2615465/ https://ncbi.nlm.nih.gov/pubmed/16494484 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol060030s |
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