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Efficient Glycosidation of a Phenyl Thiosialoside Donor with Diphenyl Sulfoxide and Triflic Anhydride in Dichloromethane

[Image: see text] The formation of sialic glycosides using a thiosialic acid derivative, diphenyl sulfoxide and trifluoromethanesulfonic anhydride is reported. With an excess of diphenyl sulfoxide glycal formation can be completely suppressed and excellent yields are obtained for coupling to a wide...

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Detalhes bibliográficos
Main Authors: Crich, David, Li, Wenju
Formato: Artigo
Idioma:Inglês
Publicado em: 2006
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2615465/
https://ncbi.nlm.nih.gov/pubmed/16494484
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol060030s
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