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Regioselective 15-Bromination and Functionalization of a Stable Synthetic Bacteriochlorin
[Image: see text] 5-Methoxy-8,8,18,18-tetramethyl-2,12-di-p-tolylbacteriochlorin (MeO-BC) undergoes regioselective electrophilic bromination with NBS to give the 15-bromo analogue (MeO-BC-Br(15)) in 85% yield. By contrast, the bacteriochlorin lacking the 5-methoxy group (8,8,18,18-tetramethyl-2,12-d...
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| Main Authors: | , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2007
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2602880/ https://ncbi.nlm.nih.gov/pubmed/17567079 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo070785s |
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