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Ring expansion of substituted norbornadienes for the synthesis of mono- and disubstituted 2-azabicyclo[3.2.1]octadienes

We have studied the conversion of substituted norbornadienes into a substituted 2-azabicyclo[3.2.1]octadiene system via reaction with toluenesulfonyl azide. We have found that both and mono- and disubstituted norbornadienes will undergo the cycloaddition/rearrangement sequence to provide the bicyclo...

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Hlavní autoři: Emelda, Nova, Bergmeier, Stephen C.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2008
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2597873/
https://ncbi.nlm.nih.gov/pubmed/19746153
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2008.06.123
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